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International Ocean Discovery Program Expedition 401 recovered 983 m of sediment from Portugal’s southwest margin in the northeast Atlantic Ocean at Site U1609 (37°22.6259′ N, 9°35.9120′ W; 1659.5 m water depth). This site was designed to recover the distal contourites deposited by the Mediterranean Overflow Water contour current from the late Miocene to the Pleistocene. We report semiquantitative elemental results from X-ray fluorescence scanning of sediment cores from Site U1609 (Holes U1609A and U1609B) scanned at a 4–5 cm resolution from ~202 to 509 m core depth below seafloor, Method A, equivalent to ~4.52 to ~7.8 Ma. Raw element intensities (in counts per second) for Al, Si, Ca, Ti, Mn, Fe, Rb, Sr, Zr, and Ba are presented here and correlated with lithofacies variations. We also identify biogenic-terrestrial input proportions and illustrate downcore cyclicity and correlation patterns between terrigenous components (Al, Si, Ti, Mn, and Ba), as well as their anticorrelations with biogenic (Ca and Sr) inputs. The cyclical variations in elemental ratios may help stratigraphic correlation between Holes U1609A and U1609B, astronomical tuning of the spliced record, and sedimentary interpretations of changes to the Mediterranean–Atlantic gateway and the bottom current circulation along the Atlantic margin of Portugal before, during, and after the Messinian Salinity Crisis. 

This report presents the results of X-ray fluorescence (XRF) scanning of sediment cores from International Ocean Discovery Program (IODP) Expedition 401 Site U1385, conducted as part of the Investigating Miocene Mediterranean–Atlantic Gateway Exchange (IMMAGE) Land-2-Sea drilling project. The expedition investigated Atlantic–Mediterranean exchange during the Late Miocene, focusing on the Messinian Salinity Crisis and its impact on climate and oceanography. Site U1385 is located on the Promontório dos Principes de Avis, a promontory extending west from the Portuguese margin in the northeast Atlantic, and recovered sediments from the lowermost Pliocene to the Tortonian. XRF scanning provides semiquantitative elemental data at a 2 cm resolution, revealing cyclic patterns in elemental abundances that reflect lithologies and can be correlated cyclostratigraphically with orbital cycles. These data highlight strong positive correlations among terrigenous elements (Al, Si, Ti, Mn, and Ba) and negative correlations between terrigenous and biogenic (Ca and Sr) elements. These results contribute to understanding the paleoceanographic and paleoenvironmental conditions at Site U1385 during the Upper Miocene and Lower Pliocene, providing insights into sediment provenance, diagenetic processes, and climatic variations. 

The type-section of the Blackwater Draw Formation (BDF) consists of a series of five paleosol horizons developed on eolian deposits and an overlying surficial soil. Previous work has shown that magnetic properties (e.g., χ, ARM, and IRM) as a function of depth in this type-section, display both magnetically enhanced and magnetically depleted signals for different paleosols. To better understand the magnetic mineralogy responsible for these varying responses, various rock-magnetic experiments, scanning electron microscopy, and Mössbauer spectroscopy were conducted on representative samples from the six soil units which constitute the BDF type-section. Our results show that sub-micron hematite [with a minor contribution from single-domain sized hematite (Hc = ∼500 mT) dominates all the soils in terms of weight percent concentration. Whereas, low coercivity (Hc = ∼35 mT or less) magnetite/maghemitized-magnetite grains, largely in the PSD state (Mr/Ms=∼0.14 +/– 0.03588, Hcr/Hc=∼2.68 +/– 0.298789), dominate the magnetic signal. Magnetically depleted soils show a relatively higher proportion of goethite, while magnetically enhanced soils show an increased contribution from SP/SSD magnetite/maghemite phases.By combining our data-set with geochemically-derived climofunctions, we have correlated the magnetically preserved, depleted, and enhanced sections of the type-section to three distinct environmental phases (I-III). The basal sediments of Phase I displays relatively homogenous (neither enhanced nor depleted) magnetic properties due to relatively arid conditions and minimal alteration of southerly derive eolian sands. Conversely, Phase II-III represents a change in weathering intensities and provenance, resulting in a mix of southerly derived sands and northerly derived silts. Phase II, experienced greater precipitation levels, resulting in the dissolution of Fe-oxide phases and thus magnetic depletion. The uppermost Phase III experienced intermediate precipitation intensities resulting in magnetic enhancement.Using previously published age models we tentatively interpret these changing environmental conditions to be influenced by the Middle-Pleistocene Transition (1.2-0.7 Ma), where the Earth’s climatic cycles shifted from a ∼41 kyr to ∼100 kyr cycles. However, ambiguities persist due to uncertainties in the currently published age model. Due to the complexity of the magnetic signal, we recommend future studies utilize a holistic approach, incorporating rock-magnetic, geochemical, and microscopy observations for more accurate reconstruction of regional paleoenvironments.